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| 1 | Coupling of ultrasmall and small CoxP nanoparticles confined in porous SiO2 matrix for a robust oxygen evolution reaction显示文摘Rational design of electrocatalysts is important for a sustainable oxygen evolution reaction(OER).It is still a huge challenge to engineer active sites in multi-sizes and multi-components simultaneously.Here,a series of CoxP nanoparticles(NPs)confined in an SiO2matrix(SiO2/CoxP)is designed and synthesized as OER electrocatalysts.The phosphorization of the hydrolyzed Co-phyllosilicate promotes the formation of ultrasmall and small Co2P and CoP.These are firmly confined in the SiO2matrix.The coupling of multi-size and multi-component CoxP catalysts can regulate reaction kinetics and electron transfer ability,enrich the active sites,and eventually promote the intrinsic OER activity.The SiO2matrix provides abundant porous structure and oxygen vacancies,and these facilitate the exposure of active sites and improve conductivity.Because of the synergy and interplay of multisized/component CoxP NPs and the porous SiO2matrix,the unique SiO2/CoxP heterostructure exhibits low overpotential(293 m V@10 mA cm-2),and robust stability(decay 12 mV after 5000 CV cycles,97.4%of initial current after 100 h chronoamperometric)for the OER process,exceeding many advanced metal phosphide electrocatalysts.This work provides a novel tactic to design low-cost,simple,and highly efficient OER electrocatalysts. | Xiaojun Zeng Haiqi Zhang Xiaofeng Zhang Qingqing Zhang Yunxia Chen Ronghai Yu Martin Moskovits | 2022 | Nano Materials Science2022，4，4： | 2 |
| 2 | Progress and challenges of ceramics for supercapacitors显示文摘Supercapacitors(SCs)are one of the most promising electrical energy storage technologies systems due to their fast storage capability,long cycle stability,high power density,and environmental friendliness.Enormous research has focused on the design of nanomaterials to achieve low cost,highly efficient,and stable electrodes.Ceramic materials provide promising candidates for SCs electrodes.However,the low specific surface area and relatively low surface activity severely hinder the SCs performance of ceramic materials.Therefore,the basic understanding of ceramic materials,the optimization strategy,and the research progress of ceramic electrodes are the key steps to enable good electrical conductivity and excellent electron transport capabilities,and realize economically feasible ceramic electrodes in industry.Herein,we review recent achievements in manufacturing the ceramic electrodes for SCs,including metal oxide ceramics,multi-elemental oxide ceramics,metal hydroxide ceramics,metal sulfide ceramics,carbon-based ceramics,carbide and nitride ceramics,and other special ceramics(MXene).We focus on the unique and key factors in the component and structural design of ceramic electrodes,which correlate them with SCs performance.In addition,the current technical challenges and perspectives of ceramic electrodes for SCs are also discussed. | Xiaojun Zeng Hanbin Song Zong-Yang Shen Martin Moskovits | 2021 | Journal of Materiomics2021，7，6： | 2 |
| 3 | STⅡ/Ⅲ:Anew electrocardiographic criteria for the identification of the culprit vessel in inferior wall myocardial infarction显示文摘 | Moskovits N Khan M Budzilowiez L | 1997 | Am J Cardiol1997，29，： | 1 |
| 4 | Tracking fragmentation of natural communities and changes in land cover:Applications of Landsat data for conservation in an urban landscape (Chicago Wilderness)显示文摘 | Wang Y Moskovits D K | 2001 | Conservation Biology2001，15，4： | 1 |
| 5 | ST I/Ⅱ :A new dectrocardiographic criteria for the identification of the culprit vessel in inferior wall myocardial infarction 显示文摘 | Moskovits N Khan M Budzilowicz L | 1997 | JACC1997，29，2： | 1 |
| 6 | STII/III:A new electrocardiographic criteria for the identification of the culprit vessel in inferior wall myocardial infarction显示文摘 | Moskovits N Khan M Budzilowiez L | 1997 | Am J Cardiol1997，29，： | 1 |
| 7 | STⅡ/Ⅲ:a new electrocardiographic criteria for the identifi-cation of the culprit vessel in inferior wall myocardial infarction显示文摘 | Moskovits N Khan M Budzilowicz L | 1997 | JACC1997，29，2： | 1 |
| 8 | Hot spots in silver nanowire bundles for surface-enhanced Raman spectroscopy 显示文摘 | Lee S J Morrill A R Moskovits M | 2006 | J Am Chem Soc2006，128，7： | 1 |
| 9 | Magnetic properties of Fe deposited into anodic aluminum oxide pores as a function of particle size 显示文摘 | A1Mawlawi D Coombs N Moskovits M | 1991 | J Appl Phys1991，70，8： | 1 |
| 10 | A study of the effects of potassium addition to supported iron catalysts in the Fischer-Tropsch reaction显示文摘 | MILLER D G MOSKOVITS M | 1988 | J Phys Chem A1988，92，21： | 1 |
| 11 | Surface geometry change in 2-naphthoic acid adsorbed on silver显示文摘 | Moskovits M Suh J S | 1988 | J Phys Chem1988，92，22： | 1 |
| 12 | Surface-enhanced spectroscopy显示文摘 | Moskovits M | 1985 | Rev Mod Phys1985，57，3： | 1 |
| 13 | Raman spectroscopy using a fiber optic probe with subwavelengh aperture 显示文摘 | D P Tsai A Othonos M Moskovits | 1994 | Appl Phys Lett1994，64，： | 1 |
| 14 | Surface - enhanced ra-man spectroscopy of colloidal metal systems : a two - dimen-sional phase equilibrium in p - aminobenzoic acid adsorbedon siiver显示文摘 | Suh J S DILella D P Moskovits M | 1983 | J Phys Chem1983，87，9： | 1 |
| 15 | Surface selection rules for surface-enhanced Raman spectroscopy: Calculations and application to the surface-enhanced Raman spectrum of phthalazine on silver显示文摘 | MOSKOVITS M SUH J S | 1984 | Journal of Physical Chemistry1984，88，23： | 1 |
| 16 | Surface-Enhanced Spectrosco- py显示文摘 | Martin Moskovits | 1985 | Reviews of Modern Physics1985，57，3： | 1 |
| 17 | 显示文摘 | AI-Mawlawi D Liu C Z Moskovits M | 1994 | J Mater Res1994，9，4： | 1 |
| 18 | Surface selection rules for surface - enhanced Raman spectroscopy : calculation and applica-tion to the surface - enhanced Raman spectrum of phthala- zine on silver显示文摘 | Moskovits M Suh J S | 1984 | J Phys Chem1984，88，23： | 1 |
| 19 | Enhanced Raman scattering by fractal clusters: Scale-invariant theory显示文摘 | STOCKMAN M I SHALAEV V M MOSKOVITS M | 1992 | Physical Review B1992，46，： | 1 |
| 20 | Template-grown high-density nanocapacitor arrays 显示文摘 | Shelimov K B Davydov D N Moskovits M | 2000 | Applied Physics Letters2000，77，： | 1 |
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