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| 1 | 半胱氨酸在碳钢与硫酸界面的缓蚀行为(英文)显示文摘Interfacial behavior of cysteine (Cys) between mild steel and sulfuric acid solution as a corrosion inhibitor has been studied with electrochemical AC (alternating current) and DC (direct current) techniques at (25.0±0.1) ℃. The AC impedance results were evaluated using equivalent circuits in which a constant phase element (CPE) has been replaced with double layer capacitance (Cdl) to represent the frequency distribution of experimental data. Changes in impedance parameters (charge transfer resistance and double layer capacitance) indicated that cysteine molecules acted by accumulating at the metal/solution interface. The fractional coverage of the metal surface (θ) was determined using AC impedance results and it was found that the adsorption of cysteine on the mild steel surface followed a Langmuir isotherm model with a standard free energy of adsorption (△G0 ads) of -35.1 kJ·mol-1. To clarify the type of interaction between mild steel surface and cysteine molecules with a molecular orbital approach, electronic properties, such as, the highest occupied molecular orbital (HOMO) energy, the lowest unoccupied molecular orbital (LUMO) energy, and the frontier molecular orbital coefficients have been calculated. Energy gaps for the interaction of mild steel surface and cysteine molecules (ELUMO Fe-EHOMO Cys and ELUMO Cys-EHOMO Fe) were used to determine whether cysteine molecules acted as electron donors or electron acceptors when they interacted with the mild steel surface. The local reactivity was evaluated through the condensed Fukui indices. Theoretical calculations were carried out using the density functional theory (DFT) at B3LYP level with the 6-311++G(d,p) basis set for all atoms by Gaussian 03W program. | ZCAN Muzaffer KARADA■ Faruk DEHRI lyas | 2008 | 物理化学学报2008,24,8: | 5 |
| 2 | Antioxidant systems in chick embryo development. Part 1.Vitamin E,carotenoids and selenium显示文摘Chick viability is known to be an important factor determining profitability of the poultry industry. Chick embryo tissues contain a high proportion of highly polyunsaturated fatty acids in the lipid fraction and therefore need antioxidant defence. The antioxidant system of the developing embryo and newly hatched chick includes the antioxidant enzymes(superoxide dismutase, glutathione peroxidase, catalase), water-soluble antioxidants(ascorbic acid, taurine, carnitine, glutathione, etc.), fat-soluble antioxidants(vitamin E, carotenoids, coenzyme Q) as well as selenium(Se). In fact, the high levels of endogenous antioxidants within the egg and embryonic tissues can clearly serve as a major adaptive mechanism for the protection of the tissue during the oxidative stress experienced at hatching. It has been shown that among different nutrients in the maternal diet which could significantly affect chick embryo development and their viability in the early posthatch life, natural antioxidants have been suggested to play a central role. Our data indicate that increased supplementation of the maternal diet can substantially increase concentrations of vitamin E, carotenoids(especially canthaxanthin) and Se in developing chick tissues and significantly decrease susceptibility to lipid peroxidation being effective nutritional tools to deal with various commercial stresses in poultry production. | Peter F.Surai Vladimir I.Fisinin Filiz Karadas | 2016 | Animal Nutrition2016,,1: | 4 |
| 3 | Decision making on financial investment in Turkey by using ARDL long-term coefficients and AHP显示文摘Mathematical modeling methods are frequently used for solving everyday problems.Decision making,one such method,can be used in every aspect of life for different scales such as micro(households),medium(companies),and macro(states)decisions.Due to the large number of parameters affecting decision,it is possible to make mistakes in the selection of the appropriate investment instrument with classical methods;hence,scarce resources may be wasted,and sometimes it may even be impossible to make a decision.This study seeks to answer the question“Which financial investment instrument should be selected under the current conditions?”using decision making problems.Factors affecting gold,USD,and EURO,which are selected as the financial investment instruments in Turkey,are examined using the autoregressive distributed lag(ARDL)bound test.The selected variables are monthly and belong to the January 2009 to May 2018 period.The ARDL results show that the selected financial investment instruments are affected by most of the factors separately.By using the coefficients obtained from the ARDL model,the analytic hierarchy process(AHP)model was established.According to the results of the model,the EURO was determined as the most suitable financial investment for Ahmet and others with the same preferences. | Serkan Atmaca HacıAhmet Karadaş | 2020 | Financial Innovation2020,6,1: | 2 |
| 4 | Influences of carotenoid supplementation on the integrated antioxidant system of a free living endangered passerine, thehihi (Notiomystiscineta) 显示文摘 | Ewen J G Thorogood R Karadas F etal | 2006 | Comp Biochem Physiol (A)2006,143,2: | 1 |
| 5 | Polyelectrolyte CASA hydro-gels for uptake of uranyl ions from aqueous solutions显示文摘 | Karada? E üzüm?B Kundakci S | 2007 | Journal of Applied Polymer Science2007,104,1: | 1 |
| 6 | A new composite sorbent for water and dye uptake:highly swollen acrylamide/2-acrylamido-2-methyl-1-propanesulfonic acid/clay hydrogels crosslinked by 1,4-butanediol dimethacrylate显示文摘 | Kundakci S üzüm?B Karada? E | 2008 | Polymer Composites2008,30,1: | 1 |
| 7 | Swelling and dye sorption stu-dies of acrylamide/2-acrylamido-2-methyl-1-propanesulfonic acid/bentonite highly swollen composite hydrogels显示文摘 | Kundakci S üzüm?B Karada? E | 2008 | Reactive and Functional Polymers2008,68,2: | 1 |
| 8 | Anesthetic and analgesic effects in patients undergoing a lumbar laminectomy of spinal,epidural or a combined spinal-epidural block with the addition of morphine显示文摘 | Düger C Gürsoy S Karada O | 2012 | Journal of clinical neuroscience2012,19,3: | 1 |
| 9 | Relationship between two estrogen receptor-alpha gene polymorphisms and angio- graphic coronary artery disease显示文摘 | Karada B Giiven M Haciolu Y | 2009 | Anadolu Kardi-yol Derg2009,9,4: | 1 |
| 10 | Effectivity of one session charcoal hemoperfusion treatment in severe carbamazepine poisoning显示文摘 | ISIK Y SOYORAL L KARADAS S | 2013 | Iranian Red Crescent Medical Journal2013,15,8: | 1 |
| 11 | Myocardial infarction due to lightning strike显示文摘 | Karadas S Vuruskan E Dursun R | 2013 | J Pak Med Assoc2013,63,9: | 1 |
| 12 | Vascular rings : presentation, imaging strategies, treatment, and outcome 显示文摘 | Kir M Saylam GS Karadas U | 2012 | Pediatr Cardiol2012,33,4: | 1 |
| 13 | The evaluation of serum surfactant protein D(SP-D)levels as a biomarker of lung injury in tuberculosis and different lung diseases显示文摘 | Güzel A Karadaˇg A Okuyucu A Alaam H Küük Y | 2014 | Clin Lab2014,60,7: | 1 |
| 14 | Effect of cefuro-xime and moxifloxacin on Staphylococcus epidermidis ad-herence to intraocular lenses显示文摘 | Karada S Ozkan B Karaba VL | 2009 | Can J Ophthalmol2009,44,6: | 1 |
| 15 | Zeta potentials of perlite samples in various electrolyte and surfactant media显示文摘 | Alkan M Karadas M Dogan M | 2005 | Colloid and Surfaces A: Physicochemical and Engineering Aspects2005,259,13: | 1 |
| 16 | Association of albuminuria with impaired aortic elasticity and left ventricular diastolic dysfunction in type 2 diabetes 显示文摘 | Duman D Demirtun R Karada B | 2008 | Anadolu Kardiyot Derg2008,8,1: | 1 |
| 17 | Embryonic development within carotenoid-enriched eggs influences the post-hatch carotenoid status of the Chicken显示文摘 | Karadas F Pappas A C Surai P F | 2005 | Comparative Biochemistry and Physiology Part B:Biochemistry and Molecular Biology2005,141,: | 1 |
| 18 | Effect of two different short pe- ripheral catheter materials on phlebitis development显示文摘 | Karada? A G? rgtilti S | 2000 | J Intraven Nurs2000,23,3: | 1 |
| 19 | Adsorption of CTAB onto perlite samples from aqueous solutions 显示文摘 | Alkan M Karadas M Dogan M | 2005 | Journal of Colloid and Interface Science2005,291,2: | 1 |
| 20 | The stability of hy- drogen evolution activity and corrosion behavior of NiCu coatings with long-term electrolysis in alkaline solution 显示文摘 | SOLMAZ R OUML N A KARADA G | 2009 | International Journal of Hydrogen Energy2009,34,5: | 1 |