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| 1 | Investigation on the Use of the Weakly Basic Polyacrylate Anion-Exchanger Amberlite IRA-68 for Sorption and Separation of Iminodiacetate Complexes of Rare Earth Elements显示文摘Based on the determined affinity series of rare earth element complexes with IMDA for the anion-exchangers, purification of macroquantities of Nd 3+ from Y 3+, Sm 3+ from Ho 3+, La 3+ from Nd 3+ and La 3+ from Pr 3+ on the weakly basic gel anion-exchanger Amberlite IRA-68 was studied. Using the presented method on 1 L of Amberlite IRA-68 in the acetate form, it is possible to obtain about 240 g Nd 2O 3 purified from Y 2O 3. Great difference in affinity of La 3+ and Nd 3+ as well as Pr 3+ complexes for this anion-exchanger in the acetate form indicates the possibility of applying this process for purification of lanthanum on the increased scale. On 1 L of Amberilte IRA-68 in the acetate form it is possible to obtain about 1125 g La 2O 3 purified from Nd 2O 3. On the basis of these results it can be assumed that unique properties of polyacrylate anion-exchangers enable their application for separation of rare earth elements. | Halina Hubicka , Dorota Kolodynska (Department of Inorganic Chemistry, Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq.3, 20-031 Lublin, Poland) | 2002 | Journal of Rare Earths2002，20，6： | 2 |
| 2 | Barrier-Torch Discharge Plasma Source for Surface Treatment Technology at Atmospheric Pressure显示文摘 | Hubicka Z Cada M Sicha M | 2002 | Plasma Sources Science and Technology2002，11，2： | 1 |
| 3 | Thin-layer chromatographydensitometric measurements for determination of N-( hydroxymethyl) nicotinamide in tablets and stability evaluation in solutions 显示文摘 | HUBICKA U KRZEK J LUKA J | 2008 | J AOAC Int2008，91，5： | 1 |
| 4 | Polyacrylate anion exchangers in sorption of heavy metal ions with non-biodegradable complexing agents 显示文摘 | Kolodynska D Hubicka H | 2009 | Chemical Engineering Journal2009，150，23： | 1 |
| 5 | CNx coatings deposited by pulsed RF supersonic plasma jet: hardness,nitrogenation and optical properties 显示文摘 | Hubicka Z Sycha M | 2001 | Surface and Coatings Technology2001，，： | 1 |
| 6 | Collisionprocesses involving a single rising bubble and a largerstationary spherical particle 显示文摘 | Basa rov6 P Machoft V Hubicka M | 2010 | International Journal ofMineral Processing2010，94，： | 1 |
| 7 | Photodegradation assessment of ciprofloxacin, moxifloxacin, norfloxacin and ofloxacin in the presence of excipients from tablets by UPLC-MS/MS and DSC显示文摘 | Hubicka U Mudzki P Talik PA | 2013 | Chem Cent J2013，7，1： | 1 |
| 8 | Separation of Y( Ⅲ ) complexes with iminodiaacetic acid on the anion-exchangers type I and type Ⅱ显示文摘 | Halina Hubicka Dorota Drobek | 1999 | Hydrometallurgy1999，，53： | 1 |
| 9 | Investigation of Polyacrylate Anion-Exchangers for Separation of Rare Earth Element Complexes with EDTA显示文摘The rare earth complexes with EDTA, Ln(edta), show an unusual sequence of affinity for the anion exchangers. The sorption and chromatographic separation of Y 3+ for Nd 3+ complexes with EDTA was studied by using the strongly basic gel and macroporous polyacrylate anion exchangers, Amberlite IRA 458 and Amberlite 958, and the weakly basic gel polyacrylate anion exchanger, Amberlite IRA 68. The investigations on sorption and separation of rare earth complexes with EDTA on the polyacrylate anion exchangers applied mainly in the environment protection so far indicate that they can be applied in anionexchange separation of lanthanide complexes with aminopolycarboxylic acids. It was shown that the weakly basic polyacrylate gel anion exchanger Amberlite IRA 68 is the most effective in purification of Y 3+ from Nd 3+ in comparison with the strongly basic anion exchangers of this type. | Halina Hubicka(Department of Inorganic Chemistry, Faculty of Chemistry, Maria Curie Sklodowska University, 20 031 Lublin, Poland) | 2002 | Journal of Rare Earths2002，20，1： | 1 |
| 10 | Notes on the photo-induced characteristics of transition metal-doped and undoped titanium dioxide thin films显示文摘 | S. Kment H. Kmentova P. Kluson J. Krysa Z. Hubicka V. Cirkva I. Gregora O. Solcova L. Jastrabik | 2010 | Journal of Colloid And Interface Science2010，，1： | 1 |
| 11 | Measurement of the Parameters of Atmospheric-Pressure Barrier-Torch Discharge显示文摘 | Chichina M Hubicka Z Churpita O | 2005 | Plasma Processes and Polymers2005，2，6： | 1 |
| 12 | Studies of application of monodisperse anion exchangers in sorption of heavy metal complexes with IDS显示文摘 | KOLODYPISKA D HUBICKA H HUBICKI Z | 2009 | Desalination2009，39，： | 1 |
| 13 | Application of monodispersive anion exchangers in sorption and separation of Y^3+ from Nd^3+ and Sm^3+ complexes with dcta显示文摘有 trans-1,2-diaminocyclohexane-N 的稀土元素建筑群, N, N,行(dcta ) 的 N -tetraacetic 酸(DCTA ) ?类型在聚苯乙烯阴离子 exchangers 上展出了亲密关系的一个不平常的序列:Pm3+>Nd3+>Sm3+>Pr3+>Ce3+>Eu3+>Gd3+>La3+>Sc3+>Tb3+>Dy3+>Ho3+>Y3+>Er3+>Tm3+>Yb3+>Lu3+[1 ] 。在这个亲密关系系列考虑Y3+,Sm3+,和Nd3+的位置,为 monodispersive 聚苯乙烯阴离子 exchangers , Lewatit MonoPlus M 500 , Lewatit MonoPlus M 600 , Lewatit MonoPlus MP 500 , Lewatit MonoPlus MP 64 ,并且为 heterodispersive 阴离子 exchanger , Lewatit MP 62 ,重量( Dg )和床( Dv )这些建筑群和工作离子交换能力( Cw )的分发系数被决定。在这些阴离子 exchangers 上在宏微的部件系统从 Sm3+ 把值,从 Nd3+ 的 Y3+ 的纯化和 Y3+ 基于这些被学习。这个方法的申请潜力面对 Nd3+ 和 Sm3+ 为 Y3+ 的分离被加亮。与在醋酸盐形式的 monodispersive 和强烈基本的聚苯乙烯胶化阴离子 exchanger Lewatit MonoPlus M 500 的 1 L,获得从 Nd2O3 净化的约 79 g Y2O3 和处于一样的过程条件从 Sm2O3 净化的 70 g Y2O3 是可能的。 | Halina Hubicka Dorota Kolodynska | 2008 | Journal of Rare Earths2008，26，5： | 1 |
| 14 | Simultaneous identification and quantitative determination of selected a minoglycoside antibiotics by thin-layer chromatography and densitometry显示文摘 | Hubicka U Krzek J Woltyflska H | 2009 | J AOAC Int2009，92，4： | 1 |
| 15 | Langmuir probediagnostics of a plasma jet system 显示文摘 | Tichy M Hubicka Z Cada M | 2009 | Plasma SourcesScience and Technology2009，18，： | 1 |
| 16 | Separation and characterization of ciprofloxacin, difloxacin, lomefloxacin, norfloxacin, and ofloxacin oxidation products under potassium permanganate treatment in acidic medium by UPLC-MS/MS显示文摘 | Hubicka U ?mudzki P ?uromska-Witek B | 2013 | Talanta2013，109，： | 1 |
| 17 | Sorption of heavy metal ions from aqueous solutions in the presence of EDTA on monodisperse anion exchangers显示文摘 | Kolodyfiska D Hubicka H Hubicki Z | 2008 | Desalination2008，227，13： | 1 |
| 18 | Barrier-torch discharge plasma source for surface treatment technology at atmospheric pressure显示文摘 | Hubicka Z Cada M Sicha M | 2002 | Plasma Sources Science and Technology2002，11，2： | 1 |
| 19 | Investiga- tion of Reactive HiPIMS+MF Sputtering of TiO2 Crystal- line Thin Films显示文摘 | OLEJNICEK J HUBICKA Z KMENT | 2013 | Surface and Coatings Technolo- gy2013，232，： | 1 |
| 20 | Studies on the extraction process of nickel(II) sulphate purification using Cyanex 272 显示文摘 | Hubicki Z Hubicka H | 1996 | Hydrometallurgy1996，40，12： | 1 |
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