|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Supporting IrO2 and IrRuOx nanoparticles on TiO2 and Nb-doped TiO2 nanotubes as electrocatalysts for the oxygen evolution reaction显示文摘IrO2 and IrRuOx(Ir:Ru 60:40 at%),supported by 50 wt%onto titania nanotubes(TNTs)and(3 at%Nb)Nb-doped titania nanotubes(Nb-TNTs),as electrocatalysts for the oxygen evolution reaction(OER),were synthesized and characterized by means of structural,surface analytical and electrochemical techniques.Nb doping of titania significantly increased the surface area of the support from 145(TNTs)to 260 m2g-1(Nb-TNTs),which was significantly higher than those of the Nb-doped titania supports previously reported in the literature.The surface analytical techniques showed good dispersion of the catalysts onto the supports.The X-ray photoelectron spectroscopy analyses showed that Nb was mainly in the form of Nb(IV)species,the suitable form to behave as a donor introducing free electrons to the conduction band of titania.The redox transitions of the cyclic voltammograms,in agreement with the XPS results,were found to be reversible.Despite the supported materials presented bigger crystallite sizes than the unsupported ones,the total number of active sites of the former was also higher due to their better catalyst dispersion.Considering the outer and the total charges of the cyclic voltammograms in the range 0.1–1.4 V,stability and electrode potentials at given current densities,the preferred catalyst was Ir O2 supported on the Nb-TNTs.The electrode potentials corresponding to given current densities were between the smallest ones given in the literature despite the small oxide loading used in this work and its Nb doping,thus making the Nb-TNTs-supported IrO2 catalyst a promising candidate for the OER.The good dispersion of IrO2,high specific surface area of the Nb-doped supports,accessibility of the electroactive centers,increased stability due to Nb doping and electron donor properties of the Nb(IV)oxide species were considered the main reasons for its good performance. | Radostina V.Genova-Koleva Francisco Alcaide Garbine Alvarez Pere L.Cabot Hans-Jürgen Grande María V.Martínez-Huerta Oscar Miguel | 2019 | Journal of Energy Chemistry2019,28,7: | 2 |
| 2 | Psychometric properties of the Beck Depression Inventory: Twenty-five years of evaluation显示文摘 | Beck AT Steer RA Garbin MG | 2005 | Clinical Psychology Review2005,30,8: | 1 |
| 3 | E -selectin plasma concentration is influenced by glycaemic control in NIDDM patients : possible role of oxidative stress显示文摘 | Cominacini L Fratta Pasini A Garbin U | 1997 | Diabetologia1997,40,4: | 1 |
| 4 | Strengthening of Masonry Arches with Textile rein- forced Mortar: Experimental Behavior and Analytical Approaches显示文摘 | GARMAENDIA L MARCOS I GARBIN E | 2014 | Materials and Structures2014,47,12: | 1 |
| 5 | Endoplasmic reticulum stress and Nrf2 signaling in cardiovascular diseases显示文摘 | COMINACINI L MOZZINI C GARBIN U | 2015 | Free Radic Biol Med2015,88,: | 1 |
| 6 | Psychometric Properties of the Beck Depression Inventory: Twenty-five Years of Evaluation显示文摘 | Beck A T Steer R A Garbin M G | 1988 | Clinical Psychology Review1988,,8: | 1 |
| 7 | Preclinical studies with prothymosin alpha on mononuclear cells from tumor patients 显示文摘 | Eckert K Grunberg E Garbin F | 1997 | Int J Immunopharmacol1997,19,910: | 1 |
| 8 | Medical treatment of ectopic pregnancy:a randomized clinical trial comparing metotrexate-mifepristone and methotrexate-placebo显示文摘 | Garbin O de Tayrac R de Poncheville L | 2004 | J Gynecol Obstet Biol Reprod2004,33,5: | 1 |
| 9 | Early HHV-6 replication is associated with morbidity non-related to CMV infection after kidney transplantation显示文摘 | Schroeder RB Michelon TF Garbin G | 2012 | Braz J Infect Dis2012,16,2: | 1 |
| 10 | Oxidized lowdensity lpoprotein(ox-LDL)binding to ox-LDL receptor-1 in endothelial cells induces the activation of NF-kappaB through an increased production of intracellular reactive oxygen species显示文摘 | Cominacini L Pasini AF Garbin U | 2000 | J Biol Chem2000,275,12: | 1 |
| 11 | Enhanced levels of oxi dized low-density lipoprotein prime monocytes to cytokine overproduction via upregulation of CD14 and toll-like receptor 4 in unstable angina 显示文摘 | Pasini AF Anselmi M Garbin U | 2007 | Arterioscler Thromb Vasc Biol2007,27,9: | 1 |
| 12 | C-reactive protein should accelerate the diangnosis of bowel injury after gynecologic surgery 显示文摘 | Rongieres C Gomel V Garbin O | 2002 | J Am Assoc Gynecol Laparosc2002,9,4: | 1 |
| 13 | Zofenopril inhibits the expression of adhesion molecules on endothelial cells by reducing reactive oxygen species 显示文摘 | Cominacini L Pasini A Garbin U | 2002 | Am J Hypertens2002,15,101: | 1 |
| 14 | Covering by a flap induces apoptosis of granulation tissue myofibroblasts and vascular cells显示文摘 | Garbin S Pittet B Montandon D | 1996 | Wound Rep Reg1996,4,2: | 1 |
| 15 | Adiponectin gene expression and adipocyte NF-kappaB transcriptional activity in elderly overweight and obese women:inter-relationships with fat distribution,hs-CRP,leptin and insulin resistance显示文摘 | Zamboni M Di Francesco V Garbin U | 2007 | Int J Obes(Lond)2007,31,7: | 1 |
| 16 | The expression of adhesion mol- ecules on endothelial ceils is inhibited by troglitazone through its antioxi- dant activity显示文摘 | Cominacini L Garbin U Pasini AF | 1999 | Cell Adhes Commun1999,7,3: | 1 |
| 17 | The platelet-endothelium interaction mediated by lection-like oxidized low-density lipoprotein receptor-1 reduces the intracellular concentration of nitric oxide in endothelial cells显示文摘 | Cominacini L Fratta Pasini A Garbin U | 2003 | J Am Coll Cardiol2003,41,3: | 1 |
| 18 | Preclinical studies with prothymosin alpha 1 on mononuclear cellsfrom tumor patients 显示文摘 | ECKERT K GRUNBERG E GARBIN F | 1997 | J Immunopharmacol1997,19,910: | 1 |
| 19 | Enhanced levels of oxidized low - density lipoprotein prime monocytes to cytokine overproduction via upregulation of CDI4 and toll - like receptor 4 in unstable angina 显示文摘 | Pasini AF Anselmi M Garbin U | 2007 | Arterioscler Thromb Vasc Biol2007,27,9: | 1 |
| 20 | Induction of endothelin 1 production in endothelial cells via cooperative action between CD40 and lectin like oxidized LDL receptor(LOX-1)显示文摘 | Sakurai K Cominacini L Garbin U | 2004 | Cardiovasc Pharmacol2004,44,2: | 1 |