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1Simultaneous in-situ determination of U-Pb age and trace elements in zircon by LA-ICP-MS in 20 μm spot size显示文摘Simultaneous in-situ determination of U-Pb ages and 20 trace elements of three international zircon standards(91500,GJ1 and TEMORA 1) and one laboratory zircon standard(SK10-2) separated from Cenozoic fine-grained gabbro was carried out on quadrupole ICP-MS equipped with 193 nm excimer laser in 20 μm spot size. The weighted mean 206Pb/238U ages of 91500,GJ1 and TEMORA 1 are 1064.4±4.8 Ma(2σ ),603.2±2.4 Ma(2σ ) and 418.2±2.4 Ma(2σ ),respectively. The relative standard de-viations(RSDs) of 206Pb/238U ages(2σ ) are less than 2.2% for single measurements and 0.6% for weighted means. The obtained weighted mean 206Pb/238U ages of three standard zircons agree with the recommended values within 2σ error. The weighted mean 206Pb/238U age of SK10-2 is 31.42±0.25 Ma(2σ ) and the RSDs of 206Pb/238U ages(2σ ) are between 2.4% and 5.7% for single measurements and less than 0.8% for weighted mean. The obtained weighted mean 206Pb/238U age is in good agreement with the age obtained by Yuan(2004). Trace element concentrations of NIST612 and NIST614 obtained under the same LA-ICP-MS operating conditions agree with the recommended values within analytical error. The results indicate that it is possible to measure U-Pb age and trace elements simultaneously by LA-ICP-MS in a small spot size of 20 μm.LIU XiaoMing GAO Shan DIWU ChunRong YUAN HongLin HU ZhaoChu 2007Chinese Science Bulletin2007,52,9:107
2LA-(MC)-ICPMS U-Pb zircon geochronology and Lu-Hf isotope compositions of the Taihua complex on the southern margin of the North China Craton显示文摘Widely distributed on the southern margin of the North China Craton,the Taihua complex extends roughly in an east-west direction and the relatively complete successions are found in Lushan County,Henan Province.Like many other Archean terranes,the Taihua Complex can be divided into two major lithological units along the Dangze River,namely gneisses series and supracrustal rocks.The former is located on the north side of the river and chiefly composed of TTG gneisses and amphibolites;the latter on the south side of the river is mainly supracrustal rock.Coupled with the previous studies,the results obtained by this study show that the Taihua complex was formed in a large time span from Neoarchean to Palaeoproterozoic.The TTG gneisses and amphibolites are dated at Neoarchean (2794–2752 Ma).The 2.9 Ga and 3.1 Ga zircons in amphibolites could be xenocrysts.In the North China Craton,the 2.8–2.7 Ga old rocks crop out in several areas e.g.western Shandong Province,Jiaodong Peninsula and Lushan area of Henan Province.In addition,2.8–2.7 Ga detrital zircons or xenocryst zircons have been recognized in Huai’an,Fuping,Wutai areas of North China Craton and also reported in the Early Paleozoic diamondiferous kimberlites in Mengyin and Fuxian.All these age results indicate that the 2.8–2.7 Ga rocks may have been developed much broader region than today’s outcrops.Zircon Hf and whole rock Nd isotopes show that the 2.8–2.7 Ga tectono-thermal event represents an important period of crustal growth with minor ancient crust reworked in the North China Craton.However the formation of supracrustal rocks is limited to 2.2–2.0 Ga in the Palaeoproterozoic time,not the Archaean,as previously believed.Combined with the chronological data of aluminium-rich metamorphic rocks (Khondalite series) on the southern margin of the North China Craton and adjacent areas,it is suggested that the above areas have widely developed Paleoproterozoic passive continental margin environment.DIWU ChunRong SUN Yong LIN CiLuan WANG HongLiang 2010Chinese Science Bulletin2010,55,23:72
3U–Pb ages and Hf isotopes for detrital zircons from quartzite in the Paleoproterozoic Songshan Group on the southwestern margin of the North China Craton显示文摘In situ U-Pb dating and Lu-Hf isotopic analysis were carried out for detrital zircons from quartzite in the Paleoproterozoic Songshan Group on the southern margin of the North China Craton (NCC). The re- sults provide further constraints on the crustal formation and evolution history of NCC. Four 207Pb/206Pb age populations were obtained from 99 analyses, with clusters at ~3.40 Ga, 2.77―2.80 Ga, ~2.50 Ga and 2.34 Ga, respectively. The 3.40 Ga old zircons have similar Hf isotopic compositions to those from Ar- chean rocks in the Jidong and Anshan areas of NCC. However, crustal remnants older than 3.6 Ga have been identified in the southern margin of NCC, the South China Craton, the northwestern part of the Qinling Orogen and its adjacent area. Thus, it is not easy to trace the source rock from which the 3.40 Ga detrital zircons were derived. It can be inferred that the crustal remnants older than 3.40 Ga might have been widely distributed in the North China Craton. The 2.77―2.80 Ga zircons make up a relatively small proportion and have the highest εHf (t) values (up to 6.1±1.6), consistent with the Hf isotopic composition of the depleted mantle at 2.83 Ga. Their single-stage Hf model age of 2.83 Ga is close to their crystallized age, suggesting that their source rocks were extracted from the contemporaneous depleted mantle. The ~2.50 Ga zircon grains constitute about 85% of the total grain population and their Hf isotopic compositions indicate major growth of juvenile crust at ~2.50 Ga but minor reworking of ancient crust. The youngest zircon dated in this study gave an U-Pb age of 2337±23 Ma, which can be considered the maximum depositional age of the formation of the Songshan Group.DIWU ChunRong SUN Yong YUAN HongLin WANG HongLiang ZHONG XingPing LIU XiaoMing 2008Chinese Science Bulletin2008,53,18:54
4Geochronological,geochemical,and Nd-Hf isotopic studies of the Qinling Complex,central China:Implications for the evolutionary history of the North Qinling Orogenic Belt显示文摘The Qinling Complex of central China is thought to be the oldest rock unit and the inner core of the North Qinling Orogenic Belt(NQOB).Therefore,the Qinling Complex is the key to understanding the prePaleozoic evolution of the NQOB.The complex,which consists of metagraywackes and marbles,underwent regional amphibolite-facies metamorphism.In this study,we constrained the formation age of the Qinling Complex to the period between the late Mesoproterozoic and the early Neoproterozoic(ca.1062-962 Ma),rather than the Paleoproterozoic as previously thought.The LA-ICP-MS data show two major metamorphic ages(ca.499 and ca.420-400 Ma) for the Qinling Complex.The former age is consistent with the peak metamorphic age of the high- and ultra-high pressure(HP-UHP) rocks in the Qinling Complex,indicating that both the HP-UHP rocks and their country rocks experienced intensive regional metamorphism during the Ordovician.The latter age may constrain the time of partial melting in the NQOB between the late Silurian and early Devonian.The Qinling Complex is mostly affiliated with subduction-accretion processes along an active continental margin,and should contain detritus deposited in a forearc basin.The available data indicate that the NQOB was an independent micro-continent at least prior to the Neoproterozoic,and included a portion of the Grenville orogenic belt during the period of 1.2-0.8 Ga.The NQOB has experienced a unique geological history,which is obviously different from that of the North China Craton(NCC) and the Yangtze Craton during the Precambrian.The Neoproterozoic granitoids that intruded the Qinling Complex can be interpreted as the products of assembly of the supercontinent Rodinia.The NQOB was separated from Rodinia at ca.830-740 Ma.Subsequently,the NQOB moved closer to the northern margin of the NCC,and the initial accretion or collision with the NCC occurred from the late Cambrian to the early Ordovician.Chunrong Diwu Yong Sun Yan Zhao BingXiang Liu Shaocong Lai 2014Geoscience Frontiers2014,5,4:27
5Crustal growth at ~2.5 Ga in the North China Craton:evidence from whole-rock Nd and zircon Hf isotopes in the Huai'an gneiss terrane显示文摘Huai'an 片麻岩岩层主要由 TTG 片麻岩和 dioritic 片麻岩组成。在 magmatic 锆石核心标明日期的 situ U-Pb 的激光显示这些片麻岩的 protolith 在 ∼2.5 Ga 被形成。TTG 片麻岩有积极 ε 2.7 ~ 4.3 的 Nd (t) 价值,和大多数 magmatic 锆石有积极 ε 2.0 ~ 8.3 的 Hf (t) 价值。这些积极 ε Nd (t) 和 ε Hf (t) 价值两个都类似于在 2.5 Ga 的同时期的弄空的披风的那些。而且,为 magmatic 锆石的 2.44 ~ 2.73 Ga 的年轻 Hf 模型年龄接近预定锆石生长。整个岩石的 ε Nd (t) 价值由于在它的来源的古老的外壳的参与比在 TTG 片麻岩在 dioritic 片麻岩(0.8 ~ 1.7 ) 是更低的。然而,从 dioritic 片麻岩的许多 magmatic 锆石有类似的 ε Hf (t) 价值(2.0 ~ 7.9 ) 到同时代的弄空的披风的;他们 2.49 ~ 2.75 Ga 的 Hf 模型年龄接近锆石的 U-Pb 年龄。最高的 ε Hf (t) 价值接近弄空的披风,和相对高的 ε Hf (t) 价值对应于相对年轻的 Hf 模型年龄。这些 Nd 和 Hf 同位素特征建议 Huai'an 片麻岩岩层的片麻岩的这二种类型在 ca 从少年外壳发源。2.5 Ga。LIU Fu GUO JingHui LU XiaoPing DIWU ChunRong 2009Chinese Science Bulletin2009,54,24:24
6~4.1 Ga xenocrystal zircon from Ordovician volcanic rocks in western part of North Qinling Orogenic Belt显示文摘High-precision U-Pb dating by in situ LA-ICP-MS yields an age of 4079±5 Ma for a xenocrystal zircon from Ordovician volcanics of the Caotangou Group in western part of the North Qinling Orogenic Belt. As a result, the North Qinling Orogenic Belt becomes one of a few localities in the world that contain Hadean age records (4276±6 Ma and 4404±8 Ma detrital zircons from Jack Hill of the Yilgarn craton, 4016 Ma Acasta gneisses of the Wopmay Orogeny and Burang quartzite with detrital zircon of 4103 Ma in Tibet). It is also the first report of the Hadean age in Phanerozoic volcanics. The finding of the 4.1 Ga xenocrystal zircon provides not only the geochronological record of the oldest crustal materials in China, but also the condition for further search for rocks forming in the region during the early time of the Earth’s evolution. Thirty-six zircon U-Pb dates from the Ordovician volcanic rocks are subgrouped into seven generations that represent different tectono-magmatic events in the North Qinling Orogenic Belt. Among them, two periods of 0.9-1.5 Ga and 0.4-0.5 Ga are consistent with Mesoproterozoic and Early Paleozoic orogenies, respectively.WANG HongLiang CHEN Liang SUN Yong LIU XiaoMing xu XueYi CHEN JuanLu ZHANG Hong DIWU ChunRong 2007Chinese Science Bulletin2007,52,21:23
7Early Precambrian tectonothermal events of the North China Craton:Constraints from in situ detrital zircon U-Pb,Hf and O isotopic compositions in Tietonggou Formation显示文摘Clastic sediments and sedimentary rocks are widely used for understanding the formation and evolution of the continental crust.The Tietonggou Formation outcrops in the Xiaoqinling region at the southern margin of the North China Craton(NCC)and has unconformable contacts with the underlying Taihua Complex and overlying Paleoproterozoic Xiong’er Group.It mainly consists of quartzite and its protoliths are mature terrigenous clastic rocks.On the basis of the ages of the youngest detrital zircons from the quartzites and the ages of the Xiong’er Group,the depositional ages of the protoliths of the Tietonggou Formation were well constrained to 1.91–1.80 Ga.The U-Pb isotopic data of detrital zircons from the Formation show a major age peak at^2.1 Ga,which is consistent with 2.2–2.0 Ga magmatism in the Trans-North China Orogen of the NCC.Taking into account the texctural and compositional maturity of the Tietonggou Formation quartzite,the^2.1 Ga lithologic units in the Trans-North China Orogen are interpreted as the major source of the Tietonggou Formation.The majority of these^2.1 Ga detrital zircons mostly have highδ18O values(>6.5‰)and negativeεHf(t)values(–7.8–0.0),with corresponding Hf model ages significantly older than their crystallization ages,indicating that these zircons formed from the partial melting of ancient continental crust.The majority of the2.8–2.7 Ga and^2.5 Ga detrital zircons from the Tietonggou Formation had positiveεHf(t)values,and mantle-likeδ18O values,suggesting that the NCC has experienced two stages of significant crustal growth in the Neoarchaean at 2.7 and 2.5 Ga,respectively.The Hf isotopic data of detrital zircons from Paleoproterozoic metasedimentary rocks in the Trans-North China Orogen varied mainly toward the reduction of the radiogenic Hf isotope and gradually show a similar trend of the isotope trajectories of crustal evolution.This reveals that the NCC probably has not developed a long-lived subduction to complete the final assembly of the NCC.Alternatively,these maybe imply that the tectonic setting of the NCC substantially changed at^2.1 Ga,the reduction of the radiogenic Hf isotope could be attributed to the rollback of the subducting slab.DIWU ChunRong SUN Yong GAO JianFeng FAN LongGang 2013Chinese Science Bulletin2013,58,31:11
8Bph30confers resistance to brown planthopperby fortifying sclerenchyma in rice leaf sheaths显示文摘Phloem-feeding insects cause massive losses in agriculture and horticulture.Host plant resistance to phloem-feeding insects is often mediated by changes in phloem composition,which deter insect settling and feeding and decrease viability.Here,we report that rice plant resistance to the phloem-feeding brown planthopper(BPH)is associated with fortification of the sclerenchyma tissue,which is located just beneath the epidermis and a cell layer or two away from the vascular bundle in the rice leaf sheath.We found that BPHs prefer to feed on the smooth and soft region on the surface of rice leaf sheaths called the long-cell block.We identified Bph30 as a rice BPH resistance gene that prevents BPH stylets from reaching the phloem due to the fortified sclerenchyma.Bph30 is strongly expressed in sclerenchyma cells and enhances cellulose and hemicellulose synthesis,making the cell walls stiffer and sclerenchyma thicker.The structurally fortified sclerenchyma is a formidable barrier preventing BPH stylets from penetrating the leaf sheath tissues and arriving at the phloem to feed.Bph30 belongs to a novel gene family,encoding a protein with two leucine-rich domains.Another member of the family,Bph40,also conferred resistance to BPH.Collectively,the fortified sclerenchyma-mediated resistance mechanism revealed in this study expands our understanding of plant-insect interactions and opens a new path for controlling planthoppers in rice.Shaojie Shi Huiying Wang Lingyun Nie Di Tan Cong Zhou Qian Zhang YiLi Bo Du Jianping Guo Jin Huang DiWu Xiaohong Zheng Wei Guan Junhan Shan Lili Zhu Rongzhi Chen Longjian Xue Linda L.Walling Guangcun He 2021Molecular Plant2021,14,10:7
9Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS显示文摘Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(>70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.LIU Ye DIWU Chunrong ZHAO Yan LIU Xiaoming YUAN Honglin WANG Jianqi 2014Chinese Journal Of Geochemistry2014,33,1:6
10Expression of tissue inhibitor of matrix metalloproteinases-1 during aging in rat liver显示文摘AIM: To investigate the expression and role of tissueinhibitor of matrix metalloproteinases-1 (TIMP-1) during natural aging in rat liver and to detect the expression of matrix metalloproteinase-2 (MMP-2) and MMP-9.METHODS: The rats were divided into 3-mo-old group (n = 5), 10-mo-old group (n = 5) and 24-mo-old group(n = 5). Histopathologic changes of liver were observed with HE and Masson stain. The location and protein expressions of TIMP-1 were determined by immunohistochemistry and Westem blot; message RNA (mRNA) levels were measured in livers from rats of various ages by semi-quantitative reverse transcriptional polymerase chain reaction (RT-PCR). In addition, the expression of MMP-2 and MMP-9was assessed by RT-PCR and Western blot.RESULTS: Histologic examination showed that the aging liver had excessive fatty degeneration and collagen deposition. Immunohistochemical staining showed that TIMP-1 related antigen in livers was located in cytoplasm. The proteinexpression of TIMP-1 was significantly higher in the oldestanimals and the mRNA expression was increased significantlyin the 24-mo-old rats (t= 4.61, P= 0.002<0.05, 24-vs 10-mo-old rats; t= 4.31, P= 0.003<0.05, 24- vs 3-mo-oldrats). The expression of MMP-2 and MMP-9 had no change during aging; the ratios TIMP-1/MMP-2 and TIMP-1/MMP-9 in aging liver were significantly higher than those in maturation and young livers.CONCLUSION: TIMP-1 may play an important role in the process of liver aging.Yu-MeiZhang Xiang-MeiChen DiWu Suo-ZhuShi ZhongYin RuiDing YangLü 2005World Journal of Gastroenterology2005,11,24:4
11Effect of Xixin decoction on O-linked N-acetylglucosamine Glycosylation of tau proteins in rat brain with sporadic Alzheimer disease显示文摘OBJECTIVE: To study the effects of Xixin decoction (XXD) on O-linked N-acetylglucosamine (O-GlcNAc) glycosylation of tau proteins in rat brain with sporadic Alzheimer disease (SAD), and discuss its possible mechanism on prevention and treatment of SAD. METHODS: The rat model of SAD was established by intracerebroventricular injection of streptozotocin. The specific pathogen free male Sprague-Dawley rats were randomly divided into sham-operation group (S), model group (M), donepezil group (D), XXD at a low dose group (XL), XXD at a medium dose group (XM) and XXD at a high dose group (XH). After treatment and praxiology test, immuno-histochemistry and western blotting were used to detect O-GlcNAc glycosylation level of tau proteins in rat brain with SAD. O-GlcNAc glycosylation and expression of tau proteins were detected by O-GlcNAc-specific antibodies RL2 and CTD110.6. RESULTS: O-GlcNAc glycosylated proteins enriched by succinylated wheat germ agglutinin significantly improved in the hippocampus of SAD rats. Thedifferences were statistically significant among XXD groups (P<0.05, P<0.01), while no obvious differences were observed between D group and M group (P>0.05). CONCLUSION: XXD can significantly improve O-GlcNAc glycosylation level of tau proteins in the hippocampus of SAD rats, which maybe inhibit hyperphosphorylation of tau proteins on key sites and its toxicity, and prevent the pathological process of SAD.Yongchang Diwu Jinzhou Tian Jing Shi 2013Journal of Traditional Chinese Medicine2013,33,3:3
12Design, synthesis and investigation of mechanisms of action of novel protein kinase C inhibitors : perylenequinonoid pigments 显示文摘Diwu Z Zimmermann J Meyer T 1994Biochem Pharmacol1994,47,2:1
13显示文摘DIWU Z J ZIMMERMANN J MEYER T 1994Biochemical Pharmacology1994,47,2:1
14Novel therapeutic and diagnostic applications of hypocrellins and hyperoeins 显示文摘Diwu Z J 1995Photochem Photobiol1995,61,6:1
15Fast Fullview Photoacoustic Imaging by Combined Scanning with a Linear Transducer Array 显示文摘DIWU YANG DA XING SIHUA YANG 2007Optics Express2007,15,15:1
16Simultaneous analysis of microbial identity and function using NanoSIMS显示文摘TianlunLi Ting‐DiWu LaurentMazéas LaurentToffin Jean‐LucGuerquin‐Kern GérardLeblon ThéodoreBouchez 2008Environmental Microbiology2008,,3:1
17Novel therapeutic and diagnostic applications of hypocrellins and hypericins显示文摘Diwu ZJ 1995photochem photobiol1995,61,:1
18A novel method for foreign body detection based on fast microwave-induced ther- moacoustic tomography with a multi-element linear transducer ar- ray显示文摘NIE Liming XING Da YANG Diwu 2007Applied Physics Letters2007,90,17:1
19Portable optical-resolution photoacoustic microscopy with a pulsed laser diode excitation显示文摘ZENG LVMING LIU GUODONG YANG DIWU 2013Applied Physics Letters2013,102,05:1
20Photosensitization with anticancer agents 12 Perylenequinoniod pigments ,a novel type of singlet oxygen sensitizer 显示文摘DIWU Z J LOWN J W 1992J Photochem Photobiol A : Chem1992,64,:1
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